ChemInform Abstract: Synthesis and Properties of (Phthalocyaninato)‐ and (Tetrabenzoporphyrinato)cobalt(III) Thiocyanate and Isothiocyanate Compounds. Crystal and Molecular Structure of (Phthalocyaninato)(pyridine)(thiocyanato)cobalt(III).

Abstract

The Co(III) complex (I) and KSCN(II) react with reduction of the macrocycle and ligand exchange to give the complex (III) as the ethanol solvate.