ChemInform Abstract: Structural and Thermal Gas Desorption Properties of Metal Aluminum Amides.

Abstract

The compounds M[Al(NH2)4]x (M: K, Mg, Ca; x = 1, 2) along with previously reported LiAl(NH2)4 and NaAl(NH2)4 are prepared by ball milling under liquid NH3 and their structural and gas desorption properties are characterized by synchrotron powder XRD, FTIR and NMR spectroscopy, and thermogravimetry coupled with mass spectroscopy.