ChemInform Abstract: Stereoselective Intermolecular Oxymercurations of Allylic Ethers.

Abstract

1997 stereochemistry stereochemistry (general, optical resolution) O 0030 31 -053 Stereoselective Intermolecular Oxymercurations of Allylic Ethers. -The regioselectivity is complete in all reactions investigated; the diastereoselectivity depends on the alkene geometry and the substitution pattern. The results may be of interest for the preparation of polyoxygenated molecules. -(CORMICK, R.; LOEFSTEDT, J.; PERLMUTTER, P.; WESTMAN, G.; Tetrahedron Lett. 38 (1997) 15,