ChemInform Abstract: Stabilization by Si Substitution of the Pseudobinary Compound Gd2(Co3‐xSix) with Magnetocaloric Properties Around Room Temperature.
Abstract:Stabilization by Si Substitution of the Pseudobinary Compound Gd 2(Co 3-xSix) withMagnetocaloric Properties Around Room Temperature. -The new solid solution Gd 2(Co3-xSix) (0.29 < x < 0.50) is obtained by arc-melting of the elements. Although Gd2Co3 does not exist, the solid solution can be stabilized by substituting a small amount of cobalt by silicon. Gd 2(Co2.53Si0.47) crystallizes in the space group Cmce with Z = 4 (single crystal XRD). All the members of the solid solution exhibit the La 3Ni3-type structu… Show more
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