Abstract:Solid Solutions RE 16 Rh 11-x Z x (RE: La, Ce, Pr, Nd, Sm; Z: Ga, Zn, Cd, In, Sn, Sb, Pb, Bi) -Centrosymmetric n = 2 Variants of Parthe's Homologous Series A5n+6B3n+5. -The title solid solutions are prepared by high-frequency melting of the elements in sealed Ta ampules and characterized by powder XRD. The structures of eight compounds are determined by single crystal XRD. crystallize with a centrosymmetric variant of the Ca16Sb11 structure type in the space group P4/mbm with Z = 2. The structure of La16Rh8Sn3… Show more
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