ChemInform Abstract: SILYLIERUNG VON NITROVERBINDUNGEN 4. MITT. TRIMETHYLSILYLIERUNG DES NITROESSIGSAEUREMETHYLESTERS UND DES DINITROMETHANS

Abstract

Der Ester (I) und Dinitromethan (II) werden mit dem Hanrstoff (III) zu den Trimethylsilylestern von Nitronsäuren (IV), (V) umgesetzt.

Synthesis, reactions, and properties of oxygen-nitrogen-oxygen systems

“…46,56,58,61,65,[71][72][73]79 In 1972 Ioffe and co-workers80 suggested using the silyl esters of nitronic acids as a 1,3-dipolar component, which unlike their alkyl analogues is stable and retains the ability of cycloaddition to olefins. [81][82][83][84][85][86][87][88][89][90][91][92] The intramolecular reactions of the nitronate group with double bonds are known too. For instance, the interaction of tetranitromethane with one of the double bonds of hexa-1,5-diene gives a nitronic ester which is then added to the other double bond forming bicyclic compound 2 (Scheme l).…”