2014
DOI: 10.1002/chin.201418198
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ChemInform Abstract: S‐[3‐Cyano‐2‐oxo‐3‐ (triphenyl‐λ5‐phosphanylidene)propyl] O‐Ethyl Carbonodithioate: A Novel Xanthate Reagent for the Synthesis of α‐Keto (Cyanomethylene)triphenylphosphorane Ylides from Olefins.

Abstract: The novel xanthate reagent (I) can undergo group transfer addition to olefins (II) under radical conditions furnishing a concise access to α‐Keto ylides (IV).

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