Chemischer Informationsdienst
 1972
DOI: 10.1002/chin.197202278
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ChemInform Abstract: RINGERWEITERUNGSFAEHIGKEIT VON PIPERIDINEN ALS FUNKTION DES SUBSTITUENTEN AM N‐ATOM, RK. VON DIAZOMETHAN MIT PIPERIDONEN‐(4) UND DESAMINIERUNG ENTSPRECHENDER AMINOMETHYLALKOHOLE MIT SALPETRIGER SAEURE

H. Favre1,
Z. Hamlet2,
R. Lanthier3
et al.

Abstract: Die. Piperidone (I) geben durch Umsetzung mit Nitromethan in Gegenwart von 1 Val Na‐methylat die Nitroalkohole (IIa) (75% Ausbeute) und durch deren Reduktion mit Fe/wäßrigem FeSO4 bzw. mit Zn/Essigsäure die Aminoalkohole (IIb) (91‐100%).

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