Abstract:Remote Hydroxylation Through Radical Translocation and Polar Crossover. -The site-selective replacement of relatively inert aliphatic C-H bonds with the hydroxy group is facilitated by employing the photocatalyst together with sulfonate esters and sulfonamides and involves a radical translocation, oxidation to carbocation, and nucleophilic trapping with H 2O under mild reaction conditions. The methoxylation of two substrates is also demonstrated. -(HOLLISTER, K. A.; CONNER, E. S.; SPELL, M. L.; DEVEAUX, K.; MA… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.