2009
DOI: 10.1002/chin.200914119
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ChemInform Abstract: Regioselective Diels—Alder Cycloadditions and Other Reactions of 4,5‐, 5,6‐, and 6,7‐Indole Arynes.

Abstract: Indole derivatives R 0140Regioselective Diels-Alder Cycloadditions and Other Reactions of 4,5-, 5,6-, and 6,7-Indole Arynes. -The reaction cycloaddition of arynes derived from 6,7-indoles (I) and (V) with 2-tert-butylfuran shows high selectivity for the more sterically congested cycloadduct (IIIa), whereas isomeric arynes derived from 4,5-or 5,6-indole derivatives show essentially no selectivity (≈1:1 mixtures). -(BROWN, N.; LUO, D.; VANDER VELDE, D.; YANG, S.; BRASSFIELD, A.; BUSZEK*, K. R.; Tetrahedron Lett.… Show more

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