ChemInform Abstract: Regio‐ and Stereoselective Synthesis of 1,4‐Dienes.

Abstract

C h emIn fo rm 2 0 1 2 , 4 3 , issu e 1 0 © 2 0 1 2 Wiley -VCH Verl ag G m b H & Co. K G a A , We i n he i m Al k ene s Q 0 083 DOI: 1 0.100 2/ch in.201 2100 53 R egio-and S t ereoselective Sy nthesis o f 1,4-D ienes. -Titano cen e-promo ted a lkenylation of te rm inal a llenes (I) with (Z)-alke nyl sulfones ( II) give s ris e to ( E,Z)-die ne s ( III) a s m ain o r so le r ea ctio n pr od u ct in m o st ca se s. -( OIS H I, S .; HATA NO , K.; TS UB OUC H I, A. ; T A KE D A*, T .; C h em. C om mun. ( Ca mbridge ) 47 (20 11) 42, 1163 9-116 40, htt p://dx.d oi.org/1 0.103 9/c1c c1 4765j ; De p. Appl. Che m., Gr a d. Sc h. E n g., To kyo Univ . Agric . Tec hno l., Ko gane i, Tok yo 1 84, Japa n; Eng .) -R. Sta ver 10 -05 3