ChemInform Abstract: Regio‐ and Diastereoselective Allenylation of Aldehydes in Aqueous Media: Total Synthesis of (+)‐Goniofufurone.

Yi, Xianghui; Meng, Yue; Hua, Xiao-Gang; Li, Chao‐Jun

doi:10.1002/chin.199913081

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“…In contrast, when propargyl bromide was γ-substituted the coupling products were predominantly, or exclusively, the allenylic alcohols. Li et al examined the propargylation-allenylation of carbonyl compounds using a variety of metals including Sn, Zn, Bi, Cd and In [29]. By using the indium-mediated allenylation reaction, Li and co-workers developed the synthesis of the anti-viral, anti-tumor compound (+)-goniofufurone [30] (eq.…”

Section: Introductionmentioning

confidence: 98%

Unorthodox chemistry for an unorthodox challenge: Exploration of new chemical reactivities for a sustainable future

2011

Sci. China Chem.

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The sustainable development of our future represents an unorthodox challenge in sciences and technologies. The exploration of unconventional chemical reactivities that could potentially result in more sustainable chemical productions with efficient utilization of resource and inherent prevention of waste will provide the foundation for the synthetic chemistry of our future. As part of this endeavor, we have explored metal-mediated reactions in water to minimize protection-deprotection and the use of organic solvents, catalytic nucleophilic additions via C-H reactions to avoid generation and use of stoichiometric organic halides and metal in water, and Cross-Dehydrogenative-Coupling (CDC) reactions to minimize overall transformation steps. green chemistry, organometallic reactions in water, aldehyde-alkyne-amine coupling, cross-dehydrogenative-coupling

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Section: Introductionmentioning

confidence: 98%

ChemInform Abstract: Regio‐ and Diastereoselective Allenylation of Aldehydes in Aqueous Media: Total Synthesis of (+)‐Goniofufurone.

Cited by 1 publication

References 1 publication

Unorthodox chemistry for an unorthodox challenge: Exploration of new chemical reactivities for a sustainable future

Unorthodox chemistry for an unorthodox challenge: Exploration of new chemical reactivities for a sustainable future

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