ChemInform Abstract: REDUCTION OF α,β‐UNSATURATED NITRILES WITH A COPPER HYDRIDE COMPLEX

Abstract

Kupferhydrid reduziert in Form eines Komplexes die Doppelbindung in zahlreichen Nitrilen, auch in Gegenwart von weiteren funktionellen Gruppen, glatt unter Bildung der gesättigte Nitrile.

Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag6H4(dppm)4(OAc)2] and [Cu3H(dppm)3(OAc)2]

“…[1][2][3][4][5][6][7][8][9][10][11][12][13][14] In contrast, only a handful of examples of silver-catalyzed hydrogenation and hydrosilylation are known. [15][16][17][18][19][20] For example, AgOTf has been shown to catalyze the hydrosilylation of aryl aldehydes in the presence of Me 2 PhSiH and PEt 3 .…”

“…1 and κ 2 binding modes. The average Ag−Ag bond length within the [Ag 4 ] 4+ belt is 3.08 Å, which is longer than the average Ag cap −Ag belt bond h i b i t e d .…”