ChemInform Abstract: Reactions of Thiazyl Halides XSN (X: F, Cl) with Perfluorinated Imines Rf2NH (Rf: F, CF3, CF3S, (CF3)2C=, (CF3)2S=): Attempted Preparations of Aminothiazyls (=N‐SN).

Abstract

Compound (I), the precursor of ClSN, undergoes a reaction with (II) to give the products (IV) and (V) via the unstable, reactive aminothiazyl (III).