ChemInform Abstract: REACTIONS OF SULFUR NITRIDE (S4N4) WITH ANTIMONY PENTACHLORIDE, ANTIMONY PENTAFLUORIDE, ARSENIC PENTAFLUORIDE, PHOSPHORUS PENTAFLUORIDE, AND FLUOROSULFURIC ACID. PREPARATION AND CRYSTAL STRUCTURES OF SALTS OF THE S4N42+ CATION: (S4N4)(SB3F14)(SBF6), (S4N4)(SO3F)2, (S4N4)(ASF6)2.CNTDOT.SO2 (S4N4)(ALCL4)2, AND (S4N4)(SBCL6)2
Abstract:Die Lewis‐Säuren PFS und PCl5 sind als Oxidationsmittel nicht stark genug, um bei der Umsetzung mit S4N4 eine kationische S‐N‐Spezies zu bilden; sie liefern statt dessen ein einfaches Addukt bzw. ein Gemisch von Chlorsulfanen und Chlorphosphazenen.
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