ChemInform Abstract: Reactions of Potassium N‐(Vinyloxyethyl)dithiocarbamate with Polyfluoroaromatic Compounds.

Abstract

Reactions of Potassium N-(Vinyloxyethyl)dithiocarbamate with Polyfluoroaromatic Compounds.-Reaction of the title dithiocarbamate (I) with polyfluoroaromatics [cf. compound (II)] provides the corresponding aromatic esters of N-(vinyloxyethyl)dithiocarbamic acid which decompose immediately to the isothiocyanate (III) and its hydrolysate, 1,3oxazolidin-2-thione (IV). The instability of the initially formed dithiocarbamic acid esters is proposed to be a result of the strong electron-accepting inductive effect of the polyfluoroaromatic ring. -(AMOSOVA, S. V.; GAVRILOVA, G. M.; GOSTEVSKAYA, V. I.; SAMOILOVA, A. A.; TORYASHINOVA, D.-S. D.; Zh. Org. Khim. 34 (1998) 6, 918-920; Irkutsk. inst. org. khim. Sib. otd. Ross. akad. nauk, Irkutsk 664033, Russia; RU)