Abstract:Reactions of Potassium N-(Vinyloxyethyl)dithiocarbamate with Polyfluoroaromatic Compounds.-Reaction of the title dithiocarbamate (I) with polyfluoroaromatics [cf. compound (II)] provides the corresponding aromatic esters of N-(vinyloxyethyl)dithiocarbamic acid which decompose immediately to the isothiocyanate (III) and its hydrolysate, 1,3oxazolidin-2-thione (IV). The instability of the initially formed dithiocarbamic acid esters is proposed to be a result of the strong electron-accepting inductive effect of t… Show more
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