ChemInform Abstract: Reactions of Coordinated Ligands. Part 6. Stabilization of RP(OH)2, RPHNEt2, and RPHCl as Ligands in (CO)5ML.

Abstract

209ChemInform Abstract Starting with Cr complexes of the type (I) new complexes of the type (II), (III), (IV), and (V) are obtained according to the scheme. Mo and W analogues to (IV) and (V) with R: Ph and tBu are synthesized similarly. These compounds contain phosphines which are non-existent or having a different tautomeric structure in the free state and are stabilized by coordination to the metal(0) center.