ChemInform Abstract: Rapid Wolff—Kishner Reductions in a Silicon Carbide Microreactor.

Newman, Stephen G.; Gu, Li; Lesniak, Christoph; Victor, Georg; Meschke, Frank; Abahmane, Lahbib; Jensen, Klavs F.

doi:10.1002/chin.201418092

Cited by 1 publication

(1 citation statement)

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“…The advantages of microreactors have been clearly demonstrated for noncatalytic gas-liquid and liquid-liquid reactions that require precise control over reaction conditions, or involve dangerous chemicals such as corrosive fluorine or explosive diazocompounds [13][14][15][16]. However, considering that the vast majority of modern chemical processes utilise heterogeneous catalysts to replace stoichiometric reactions due to obvious economic and environmental advantages, the application of catalytic coatings in microreactors is disproportionately scarcely studied [17].…”

Section: Introductionmentioning

confidence: 99%

Scale up study of capillary microreactors in solvent-free semihydrogenation of 2‐methyl‐3‐butyn‐2‐ol

Cherkasov

Al-Rawashdeh²,

Ibhadon

et al. 2016

Catalysis Today

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warwick.ac.uk/lib-publicationsOriginal citation: Cherkasov, Nikolay, Al-Rawashdeh, Ma 'moun, Ibhadon, Alex O. and Rebrov, Evgeny V.. (2016) Scale up study of capillary microreactors in solvent-free semihydrogenation of 2-methyl-3-butyn-2-ol. Catalysis Today, 273 . pp. 205-212. Permanent WRAP URL:http://wrap.warwick.ac.uk/78678 Copyright and reuse:The Warwick Research Archive Portal (WRAP) makes this work by researchers of the University of Warwick available open access under the following conditions. Copyright © and all moral rights to the version of the paper presented here belong to the individual author(s) and/or other copyright owners. To the extent reasonable and practicable the material made available in WRAP has been checked for eligibility before being made available.Copies of full items can be used for personal research or study, educational, or not-for-profit purposes without prior permission or charge. Provided that the authors, title and full bibliographic details are credited, a hyperlink and/or URL is given for the original metadata page and the content is not changed in any way. A note on versions:The version presented here may differ from the published version or, version of record, if you wish to cite this item you are advised to consult the publisher's version. Please see the 'permanent WRAP url' above for details on accessing the published version and note that access may require a subscription. Keywords: Semihydrogenation; catalytic coatings; microreactor; Palladium; alkynol; acetylene. Highlights:-Capillary reactors with a diameter of 0.53 and 1.6 mm were coated with a Pd/ZnO catalyst -The alkene selectivity above 97% was obtained in the hydrogenation of 2-methyl-3-butyn-2-ol -At a coating thickness of 6 µm, the onset of internal diffusion limitations was observed -A throughput of 28 kg/day per coated channel can be reached according to the reaction kinetics Graphical abstract:

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Section: Introductionmentioning

confidence: 99%