ChemInform Abstract: PROTON AND CARBON‐13 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY STUDIES OF ALUMINUM HALIDE‐ALKYLPYRIDINIUM HALIDE MOLTEN SALTS AND THEIR BENZENE SOLUTIONS

Abstract

Vier Tieftemp.‐Salzschmelzen 2 : 1 AlCl3 ‐Butylpyridiniumchlorid, 1 :1 AlCl3‐Butylpyridiniumchlorid, 2:1 AlCl3‐ Ethylpyridiniumbromid und 2:1 AlBr3‐Ethylpyridiniumbromid werden untersucht und die Werte für die physikalischen Eigenschaften (elektrische Leitfähigkeit, Dichte, Viskosität, elektrochemische Daten) mitgeteilt.

Surface Tension and Density of Ionic Liquid n-Butylpyridinium Heptachlorodialuminate

“…The analysis of the product by H NMR gave a spectrum identical to that of literature 8 (see Figure S1 in the Supporting Information). The onset of thermal decomposition, T d = 520 K, for the IL (see Figure S2 in the Supporting Information) was determined by thermogravimetric analysis using a TA Instruments (SDT) model Q600 thermogravimetric analyzer.…”

An electrochemical and spectroscopic study of some aromatic hydrocarbons in the room temperature molten salt system aluminum chloride-n-butylpyridinium chloride

“…The 2:1 AlCb-ethylpyridinium bromide and the AlC^-n-butylpyridinium chloride systems (also molten at room temperature), and their mixtures with benzene, have been studied by and l3C NMR spectroscopy. 16 It was shown that the addition of benzene to the melt caused a marked increase in the conductivity and a marked decrease in the viscosity, but no benzene-AlCh complexes were observed.…”