ChemInform Abstract: PROPARGYLSILANE AND (TRIMETHYLSILYL)ALKYNE TERMINATOR GROUPS. FORMATION OF AN EXOCYCLIC ALLENE IN THE ACETOLYSIS OF 8‐(TRIMETHYLSILYL)‐6‐OCTYN‐2‐YL TOSYLATE

Despo, Aris D.; Chiu, Sai Keung; FLOOD, T.; Peterson, Paul E.

doi:10.1002/chin.198043244

Chemischer Informationsdienst

1980

DOI: 10.1002/chin.198043244

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ChemInform Abstract: PROPARGYLSILANE AND (TRIMETHYLSILYL)ALKYNE TERMINATOR GROUPS. FORMATION OF AN EXOCYCLIC ALLENE IN THE ACETOLYSIS OF 8‐(TRIMETHYLSILYL)‐6‐OCTYN‐2‐YL TOSYLATE

Aris D. Despo¹,

Sai Keung Chiu²,

T. FLOOD³

et al.

Abstract: Acetolyseuntersuchungen des Tosylats (I) mit dem Propargylsilan‐Terminator zeigen, daß eine Cyclisierung erfolgt, wobei die Trimethylsilylgruppe infolge einer β‐Stabilisierung eines kationischen Zwischenproduktes die Cyclisierung zum fünfgliedrigen Ring hin di‐ rigiert.

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ChemInform Abstract: PROPARGYLSILANE AND (TRIMETHYLSILYL)ALKYNE TERMINATOR GROUPS. FORMATION OF AN EXOCYCLIC ALLENE IN THE ACETOLYSIS OF 8‐(TRIMETHYLSILYL)‐6‐OCTYN‐2‐YL TOSYLATE

Abstract: Acetolyseuntersuchungen des Tosylats (I) mit dem Propargylsilan‐Terminator zeigen, daß eine Cyclisierung erfolgt, wobei die Trimethylsilylgruppe infolge einer β‐Stabilisierung eines kationischen Zwischenproduktes die Cyclisierung zum fünfgliedrigen Ring hin di‐ rigiert.

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References 1 publication

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