ChemInform Abstract: PREPARATION OF α,β‐UNSATURATED CARBOXYLIC ESTERS BY THE REACTION OF ACI‐NITROESTERS WITH (ETHOXYCARBONYLMETHYLENE)TRIPHENYLPHOSPHORANE
Abstract:Alkohole (II) und das Nitrophenol (I) reagieren miteinander in Gegenwart von Azodicarbonsäurediethyl‐ ester (III) und Triphenylphosphin (IV) zu den aci‐Nitroestern (V), die mit dem Phosphorylid (VI) zu den substituierten Acrylsäureestern (VII) und dem p‐Benzochinonmonoxim (VIII) umgesetzt werden.
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