ChemInform Abstract: Preparation of trans‐1,2‐Diaminocyclohexane Derivatives by Lithium Perchlorate Catalyzed Ring Opening of Aziridines.

Abstract

Preparation of trans-1,2-Diaminocyclohexane Derivatives by Lithium Perchlorate Catalyzed Ring Opening of Aziridines. -N,N'-Dialkylated trans-1,2-diaminocyclohexane derivatives (V) can be obtained in good yields by aminolysis of the corresponding aziridines (IV) in the presence of LiClO 4 . -(DE PARRODI, C. ANAYA; VAZQUEZ, V.; QUINTERO, L.; JUARISTI, E.; Synth. Commun. 31 (2001) 21, 3295-3302; Dep. Quim. Biol., Univ. Americas-Puebla, 72780 Puebla, Mex.; EN)