Chemischer Informationsdienst
 1981
DOI: 10.1002/chin.198106311
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ChemInform Abstract: PREPARATION OF THE TERMINAL PENTADEOXY DISACCHARIDE UNIT C‐B OF ANTHRACYCLINE ANTIBIOTICS

Joachim Thiem1,
H.‐W. Kluge2,
Jens Schwentner3

Abstract: Durch sauer katalysierte Addition des Anhydroallopyranosids (II) an das Rhamnal (I) wird unter Allylumlagerung das Disaccharid (III) gewonnen, aus dem mit LiI ein Gemisch der isomeren Bromide (IVa) und (Va) erhalten wird, die nachfolgend in die Iodide (IVb) bzw. (Vb) übergeführt werden.

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