Abstract:diastereoselective syntheses, enantioselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans-isomerism) O 0031
-035Preparation of TADOOH, a Hydroperoxide from TADDOL, and Use in Highly Enantioface-and Enantiomer-Differentiating Oxidations.-Chlorination of TADDOL, followed by reaction with urea-hydrogen peroxide complex, generates the title hydroperoxide TADOOH, a powerful reagent for asymmetric oxidation reactions. TADOOH is successfully applied in the base-catalyzed asymm… Show more
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