ChemInform Abstract: Preparation of Ionic Liquid‐Based Vilsmeier Reagent from Novel Multi‐purpose Dimethyl Formamide‐Like Ionic Liquid and Its Application.

Hullio, Ahmed Ali; Mastoi, G. M.

doi:10.1002/chin.201250028

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2018

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“…The ionic liquid based Vilsmeier reagent (1c) has been obtained according to our reported procedure by treating the 3 moles of Dimethylformamide (DMF-like ionic liquid) (1a) with one mole of trichlorotriazine (1b) as shown in (Scheme 1) [12].…”

Section: Resultsmentioning

confidence: 99%

Ionic Liquid Based Vilsmeier Reagent as an Efficient Reagent for Esterification of Alcohols and Carboxylic Acids

Hullio¹,

Mastoi²,

Hassan³

2018

IJOC

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The Vilsmeier reagent is well-known electrophilic reagent for synthetically useful organic transformations. Its ionic liquid version has been prepared from DMF-like ionic liquid. Apart from its other reported applications, presently it has been used as an efficient organo reagent for efficient esterification. Variety of esters has been prepared from versatile carboxylic acids and alcohols under ionic liquid conditions with excellent yields. The present system offers an economically and environmentally better alternative to routine procedures.

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Section: Resultsmentioning

confidence: 99%

Ionic Liquid Based Vilsmeier Reagent as an Efficient Reagent for Esterification of Alcohols and Carboxylic Acids

Hullio¹,

Mastoi²,

Hassan³

2018

IJOC

Self Cite

View full text Add to dashboard Cite

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ChemInform Abstract: Preparation of Ionic Liquid‐Based Vilsmeier Reagent from Novel Multi‐purpose Dimethyl Formamide‐Like Ionic Liquid and Its Application.

Abstract: The complex consisting of cyanuric chloride and an imidazole‐based DMF‐like ionic liquid forms the reactive intermediate MPFIL (multipurpose functional ionic liquid) whose capacity to achieve more useful organic transformation is tested in numerous types of reactions.

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Ionic Liquid Based Vilsmeier Reagent as an Efficient Reagent for Esterification of Alcohols and Carboxylic Acids

Ionic Liquid Based Vilsmeier Reagent as an Efficient Reagent for Esterification of Alcohols and Carboxylic Acids

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