ChemInform Abstract: PREPARATION AND PROPERTIES OF SUBSTITUTED 1,2,3‐DIAZAPHOSPHOLINES

Bobkova, R. G.; Ignatova, N.; Shvetsov-Shilovskii, N. I.; Негребецкий, В. В.; Васильев, А. Ф.

doi:10.1002/chin.197626279

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Behavior Of Sulfur and Fluorine Analogues Under Arbuzov Cond...1

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1977

1981

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“…Trialkyl Trlthiophosphites Trialkyl trithiophosphites are reported211 to react by a mutual exchange process which is in sharp contrast to the behavior of trialkyl phosphites. The mutual exchange process has been applied for the synthesis of thiophosphorochloridites (92) and dichloridites (93). Triphenyl trithiophosphite also reacts similarly.212 A explanation could be that as the sulfur atom has vacant d orbitals (unlike the oxygen which has none), it could enter into a partial double bond formation with the unshared pair of electron on phosphorus.…”

Section: Behavior Of Sulfur and Fluorine Analogues Under Arbuzov Cond...mentioning

confidence: 99%

Michaelis-Arbuzov rearrangement

Bhattacharya¹,

Thyagarajan²

1981

Chem. Rev.

795

413

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Contents I. Introduction 415 II. Reaction Mechanism 416 III. Scope and Limitation of the Reaction 417 A. Alkyl Halides 418 B. Tricoordinate Phosphorus Reactant 420 C. Effectiveness of Catalysts 421 IV. Synthetic Applications 421 A. Synthesis of Phosphonates 421 B. Synthesis of Phosphinates 422 C. Synthesis of Tertiary Phosphine Oxides 423 D. Synthesis of Phosphonyl and Phosphinyl Halides 424 E. Other Synthetic Applications 424 V. Behaviour of Sulfur and Fluorine Analogues under Arbuzov Conditions 425

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Section: Behavior Of Sulfur and Fluorine Analogues Under Arbuzov Cond...mentioning

confidence: 99%