ChemInform Abstract: Potentially Hexadentate Bisazine Dioximate Ligands: “Correct” Synthetic Procedure and Encapsulation Reactions of the Iron(II) Ion.

Abstract

ketone derivativesketone derivatives (acyclic compounds) P 0220 -069Potentially Hexadentate Bisazine Dioximate Ligands: "Correct" Synthetic Procedure and Encapsulation Reactions of the Iron(II) Ion.-Condensation of diacetyl monoxime hydrazone with glyoxal or 1,2-diketones affords potentially hexadentate bisazine dioximes like (I). Reaction of the products with Fe 2+ ions does not lead to the expected trinuclear clathrochelates but to the dinuclear clathrochelates studied previously. -(VOLOSHIN, YA. Z.; VARZATSKII, O. A.; VORONTSOV, I. I.; ANTIPIN, M. YU.; TKACHENKO, E. YU.; Russ.