ChemInform Abstract: Planar Chiral Triazole‐Based Phosphanes Derived from [2.2]Paracyclophane and Their Activity in Suzuki Coupling Reactions.

Abstract

Planar Chiral Triazole-Based Phosphanes Derived from [2.2]Paracyclophane and Their Activity in Suzuki Coupling Reactions. -Four cyclophane derivatives with triazole-phosphane moieties are synthesized and tested as ligands in Suzuki cross--coupling reactions with compound (V) giving the best results. -(GLOVER, J. E.; MARTIN, D. J.; PLIEGER, P. G.; ROWLANDS*, G. J.; Eur. J. Org. Chem. 2013, 9, 1671-1675, http://dx.doi.org/10.1002/ejoc.201201601 ; Inst. Fundam. Sci., Massey Univ., Palmerston North, N. Z.; Eng.) -Roessler 32-094