ChemInform Abstract: PHOTOLYSE VON TRIMETHYLAMMONIO‐P‐CHLORBENZAMIDAT, TRIPLETT‐P‐CHLORBENZOYLNITREN

Semenov, V. P.; Khusainova, A. K.; Studenikov, A. N.; Ogloblin, K. A.

doi:10.1002/chin.197514108

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Rc6h4ch=nn(ch3)31

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1980

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“…Imidoyl aminimides (135) containing a benzyl group rearranged upon heating and gave an unstable product (136) which decomposed in the presence of air to 2,4,6triphenyl-s-triazine (145). In the heterocyclic series without allylic substituents, migration of groups occurred to either the oxygen or nitrogen depending on the structure of the migrating group (137)(138)(139)(140) (155,156). 139 F. Photolysis.…”

Section: Rc6h4ch=nn(ch3)3mentioning

confidence: 99%

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Chemistry of Aminimides

Wawzonek¹

1980

Ind. Eng. Chem. Prod. Res. Dev.

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The period 1972-1979 saw considerable activity in research of the chemistry and utilization of aminimides. Studies have extended investigation to aminimides in which the acyl group is derived from imino acids, cyanuric acid, phosphonic acids, and picric acid and to vinylogues of aminimides. Work continued with aminimides derived from nitrogen heterocycles and their conversion to diazepines and bridged nitrogen bicyclic compounds. Commercial utilization of aminimides based on 1,1dimethylhydrazine has been hampered in this country by the loss of the sole commercial source of this compound.

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Section: Rc6h4ch=nn(ch3)3mentioning

confidence: 99%

“…oxazoline152 (138,139) and that from the pyrazolidone 153 formed the bicyclic compound154 (137). the nitrene 156 occurred with the vinylogue of an aminimide (155)(71).…”

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confidence: 99%

Chemistry of Aminimides

Wawzonek¹

1980

Ind. Eng. Chem. Prod. Res. Dev.

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ChemInform Abstract: PHOTOLYSE VON TRIMETHYLAMMONIO‐P‐CHLORBENZAMIDAT, TRIPLETT‐P‐CHLORBENZOYLNITREN

Abstract: Bei der Bestrahlung des Amidats (I) in Gegenwart von 1‐Methoxy‐2‐methyl‐propen‐ (1) in Methylenchlorid bei ‐ 10°C mit Hg‐Licht entsteht das Amid (IV) neben geringen Mengen des Oxazolins (V).

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Chemistry of Aminimides

Chemistry of Aminimides

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