1978
DOI: 10.1002/chin.197833128
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ChemInform Abstract: PHOTOCYCLOADDITION OF β‐METHYLSTYRENES TO SOME 9‐CYANOPHENANTHRENES. CHEMICAL CONSEQUENCES OF EXCIPLEX FORMATION

Abstract: Die Photoaddition eines Phenanthrens wie z.B. (Ia) an Styrole wie z.B. trans‐(Ila), die hauptsächlich zum" Kopf‐Kopf‐Addukt (IIIa) führt, wird durch einen Zusatz von Isopren nur zu einem Teil gelöscht.

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“…Pertinent bond lengths in the coordination unit of 3 are as follows: Fe-Nj, 2.04 (1); Fe-N2, 2.05 (2); Fe-0 2.13 (1) Á. The equatorial bond lengths values are consistent with one-electron occupancy of the dx^yi orbital, and therefore they confirm the Fe-O, Fe(III) state, while the axial bond elongation explains the large value of the quadrupole splitting.…”
mentioning
confidence: 58%
“…Pertinent bond lengths in the coordination unit of 3 are as follows: Fe-Nj, 2.04 (1); Fe-N2, 2.05 (2); Fe-0 2.13 (1) Á. The equatorial bond lengths values are consistent with one-electron occupancy of the dx^yi orbital, and therefore they confirm the Fe-O, Fe(III) state, while the axial bond elongation explains the large value of the quadrupole splitting.…”
mentioning
confidence: 58%