Abstract:1998 photochemistry, radiation chemistry, chemoluminescence photochemistry, radiation chemistry, chemoluminescence O 0160
-046Photochemistry of Fluorophenyl Azides in Diethylamine. Nitrene Reaction versus Ring Expansion.-Fluorophenyl azides are the most popular reagents for photoaffinity labeling. In order to further investigate the fluorine effect on the singlet nitrene ring expansion, several fluorophenyl azides were photolyzed with diethylamine at 25 • C. While most of the compounds afford azepines by ring … Show more
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