ChemInform Abstract: Phosphorylated PEG (PPEG) as a New Support for Generation of Nano‐Pd(0): Application to the Heck—Mizoroki and Suzuki—Miyaura Coupling Reactions.

Abstract

Phosphorylated PEG (PPEG) as a New Support for Generation of Nano-Pd(0): Application to the Heck-Mizoroki and Suzuki-Miyaura Coupling Reactions. -This describes new nano-Pd catalysts generated in situ from PdCl 2 and bis-diphenylphosphorylated PEGs. The catalysts are successfully applied in coupling reactions and can be easily recycled and reused at least four times without a significant loss in activity. -(IRANPOOR*, N.; FIROUZABADI, H.; RIAZI, A.; SHAKERPOOR, A.; Appl. Organomet. Chem. 27 (2013) 8, 451-458, http://dx.doi.org/10.1002/aoc.3002 ; Dep. Chem., Coll. Sci., Shiraz Univ., Shiraz 71454, Iran; Eng.) -Roessler 52-082