ChemInform Abstract: Pd(OAc)<sub>2</sub>/o‐Chloranil/M(OTf)<sub>n</sub>: A Catalyst for the Direct C—H Arylation of Polycyclic Aromatic Hydrocarbons with Boryl‐, Silyl‐, and Unfunctionalized Arenes.

Kawasumi, Katsuaki; Mochida, Kenji; Kajino, Tomonori; Segawa, Y.; Itami, Kenichiro

doi:10.1002/chin.201222090

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2019

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“…The combined organic layers were washed with brine, dried over MgSO 4 , filtered, and concentrated under reduced pressure. The crude product was purified by recycling GPC to afford 3-phenylfluoranthene (8) 27…”

Section: ■ Experimental Sectionmentioning

confidence: 99%

Ni-Catalyzed α-Selective C–H Borylations of Naphthalene-Based Aromatic Compounds

et al. 2019

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The ability of α-borylated naphthalene-based aromatic compounds is important because it provides ready access to interesting novel extended π-systems. In this report, we disclose the Ni-catalyzed α-selective C–H borylations of naphthalene-based aromatic compounds. The reaction proceeds with peri-xanthenoxanthene and other aromatic compounds to regioselectively afford the α-borylated products without directing groups. The selectivities of these transformations are different from those of Ir-catalyzed C–H borylation reactions and can be used in a complementary manner.

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Section: ■ Experimental Sectionmentioning

confidence: 99%

Ni-Catalyzed α-Selective C–H Borylations of Naphthalene-Based Aromatic Compounds

et al. 2019

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ChemInform Abstract: Pd(OAc)₂/o‐Chloranil/M(OTf)_n: A Catalyst for the Direct C—H Arylation of Polycyclic Aromatic Hydrocarbons with Boryl‐, Silyl‐, and Unfunctionalized Arenes.

Abstract: The same catalytic system is applied to the reaction of fluoranthene or pyrene with aryl boron compounds, aryl silanes or even unfunctionalized arenes.

Cited by 1 publication

References 1 publication

Ni-Catalyzed α-Selective C–H Borylations of Naphthalene-Based Aromatic Compounds

Ni-Catalyzed α-Selective C–H Borylations of Naphthalene-Based Aromatic Compounds

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ChemInform Abstract: Pd(OAc)2/o‐Chloranil/M(OTf)n: A Catalyst for the Direct C—H Arylation of Polycyclic Aromatic Hydrocarbons with Boryl‐, Silyl‐, and Unfunctionalized Arenes.

Abstract: The same catalytic system is applied to the reaction of fluoranthene or pyrene with aryl boron compounds, aryl silanes or even unfunctionalized arenes.

Cited by 1 publication

References 1 publication

Ni-Catalyzed α-Selective C–H Borylations of Naphthalene-Based Aromatic Compounds

Ni-Catalyzed α-Selective C–H Borylations of Naphthalene-Based Aromatic Compounds

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ChemInform Abstract: Pd(OAc)₂/o‐Chloranil/M(OTf)_n: A Catalyst for the Direct C—H Arylation of Polycyclic Aromatic Hydrocarbons with Boryl‐, Silyl‐, and Unfunctionalized Arenes.