ChemInform Abstract: Pd(I) Carbonyl Complexes with Elementorganic Ligands in the Catalytic Carbalkoxylation of Acetylene and Vinyl Exchange.

Ламберов, А. А.; Polovnyak, V. K.; Stepanov, D. E.; Alekseeva, N. F.; Akhmetov, N. S.

doi:10.1002/chin.198728098

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The Syntheses and Structures Of Palladium(+1) Carbonyl Compl...1

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1998

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“…103 The complexes [(PdXL) 2 CO] n , containing stabilising ligands of the type of arsine (L = AsPh 3 ) or stibine (L = SbPh 3 ) have been obtained on partial substitution of carbonyl and acido-ligands in palladium(+1) carbonyl halides and carbonyl acetate complexes by organoelement ligands. 104 The complexes have been characterised by elemental analysis, ESCA, and IR spectroscopy. Judging from the n = 1710 ± 1890 cm 71 region, the carbonyl group in these compounds is involved in bridging coordination.…”

Section: The Syntheses and Structures Of Palladium(+1) Carbonyl Compl...mentioning

confidence: 99%