ChemInform Abstract: Palladium Complex‐Catalyzed Germylation of Allylic Halides Using (Germyl)stannanes.

Abstract

reactions of organo-metal compounds reactions of organo-metal compounds O 0350 -064Palladium Complex-Catalyzed Germylation of Allylic Halides Using (Germyl)stannanes.-(Dimethylphenyl)germylstannane (II) reacts metal-selectively with allylic halides to afford the corresponding allylgermanes in a regio-and stereoselective manner. It reacts more readily than (triethylgermyl)stannane (IX) in these reactions. Previously published results are also given in this work. -(NAKANO, TAICHI; ONO, KAZUYOSHI; SENDA,