ChemInform Abstract: Palladium‐Catalyzed Regioselective and Stereoselective Oxidative Heck Arylation of Allylamines with Arylboronic Acids.

Abstract

Palladium-Catalyzed Regioselective and Stereoselective Oxidative Heck Arylation of Allylamines with Arylboronic Acids. -A general and convenient method for the oxidative Heck arylation of both N-mono-and N,N-diprotected allylic amines under mild conditions is developed. The method is highlighted by its excellent regioand stereoselectivity as well as its remarkable functional group tolerance. -(ZHANG, L.; DONG, C.; DING, C.; CHEN, J.; TANG, W.; LI, H.; XU*, L.; XIAO, J.; Adv. Synth. Catal. 355 (2013) 8, 1570-1578, http://dx.