ChemInform Abstract: Oxygenative Cleavage of Catechols Including Protocatechuic Acid with Molecular Oxygen in Water Catalyzed by Water‐Soluble Non‐heme Iron(III) Complexes in Relevance to Catechol Dioxygenases.

Abstract

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Multiple Sulfonation of Picolyl-Based Complexes Rendering Them Highly Water-Compatible

“…22 Finally, two isolated reports appeared to have succeeded where others failed but lacked focus, exploration of scope, and synthesis details. 23,24 These two reports are also the only ones ever to furnish multidentate picolyl-comprising ligands displaying sulfonates at their periphery. We thus set out to develop this strategy into a reliable synthetic protocol.…”