ChemInform Abstract: Oxime‐Derived Palladacycles: Applications in Catalysis

Abstract

Review: catalytic activity of oxime‐derived palladacycles for alkenylation, cross‐coupling, alkynylation, carbonylation, annulation, α‐arylation, C—H activation, and oxime rearrangement reactions as well as their role as metalloenzymes in hydrolytic processes along with other applications in organic synthesis; 117 refs.

New Palladacycle-Derived Acylhydrazones as Pre-catalysts in Mirozoki-Heck Coupling and Oxyarylations

“…Their high thermal stability in the solid state, easy preparation and ready modulation of both steric and electronic properties make them affordable tools in organic synthesis. In fact, a large number of new palladacycles have been prepared and used as pre-catalysts (Alonso et al 2000, Nájera 2016.…”