ChemInform Abstract: OCTAFLUOROCYCLOOCTATETRAENE TRANSITION‐METAL CHEMISTRY: 1,2‐η AND 1,2,3,6‐η COMPLEXES OF IRON AND PLATINUM

Barefoot, Aldos C.; Corcoran, Edward W.; Hughes, R. P.; Lemal, David M.; Saunders, W. Daniel; Laird, Brian B.; Davis, Robert Earl

doi:10.1002/chin.198122323

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Syntheses Based On Photocycloaddition To Alkenes1

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2001

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“…Diiron nonacarbonyl in hexane at room temperature gave tetracarbonyl complex 66, which at reflux was transformed into the oxidative addition product 67. 60 Cyclooctatetraene itself does not form an iron complex analogous to either. The Hughes group has since synthesized a large array of transition metal complexes of 6 spanning a remarkable range of structural types.…”

Section: Syntheses Based On Photocycloaddition To Alkenesmentioning

confidence: 98%

Hexafluorobenzene Photochemistry: Wellspring of Fluorocarbon Structures

Lemal

2001

Acc. Chem. Res.

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Ultraviolet irradiation of hexafluorobenzene in the vapor phase gives exclusively its Dewar valence isomer, from which a wealth of highly fluorinated compounds has been derived. Photoexcited in solution, hexafluorobenzene is capable of cycloaddition with a variety of unsaturated molecules. Like the Dewar benzene, resulting adducts have served as intermediates en route to many new fluorocarbons and fluorocarbon derivatives.

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Section: Syntheses Based On Photocycloaddition To Alkenesmentioning

confidence: 98%