Abstract:Novel and Efficient Synthesis of Pyrroloiminoquinones Using a Hypervalent Iodine(III) Reagent.-A novel and efficient route to pyrroloiminoquinones (II) involving the intramolecular cyclization of 3-(azidoethyl)indoles (I) mediated by a hypervalent iodine (III) reagent is presented. In some cases the N-1 protecting group of the indoles (III) is cleaved off under the reaction conditions to give the pyrroloiminoquinone (IV). -(KITA, Y.; WATANABE, H.; EGI, M.; SAIKI, T.; FUKUOKA, Y.; TOHMA, H.; J. Chem. Soc., Perk… Show more
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