ChemInform Abstract: Nickel‐Catalyzed Decarbonylative Coupling of Aryl Esters and Arylboronic Acids.

Modelling strategies for the covalent functionalization of 2D phosphorene

“…In this case, the two vacant σ hybrids of the L 2 M fragment lie high in energy for having exclusive s/p character without any d contribution. In general, the known Ni, Pd, Pt tetrahedra are stabilized by strong σ donors such as four COs42 or 2COs + 2R 3 P ligands 43,44. Since some complex is known with a dinitrogen chelate,45 we used the species (CO) 2 Ni(NH 3 ) 2 as a model reactant for the reaction with P n , reported in eqn (4).…”

“…In general, the known Ni, Pd, Pt tetrahedra are stabilized by strong  donors such as four COs 42 or 2COs + 2R3P ligands. 43,44 Since some complex is known with a dinitrogen chelate, 45 we used the species (CO)2Ni(NH3)2 as model reactant for the reaction with Pn, reported in Eq. 4.…”