ChemInform Abstract: New Straightforward Route for the Synthesis of Some 1‐Oxa‐2‐silacyclopentane Derivatives.

Abstract

Organo-silicon compounds S 0060New Straightforward Route for the Synthesis of Some 1-Oxa-2-silacyclopentane Derivatives. -Title compounds (III) are obtained by the reaction of glycidyl ethers (I) with a silylmethyllithium reagent (II) bearing hydride groups on silicon. The reaction mechanism, which is quite different from that observed with trimethylsilyl analogues, is discussed. -(SAFA*, K. D.; SHAHRIVAR, M.; TOFANGDARZADEH, S.; HASSANPOUR, A.; J. Heterocycl. Chem. 45 (2008) 2, 389-395; Organosilicon Res. Lab., Fac. Chem., Tabriz Univ., Tabriz 51664, Iran; Eng.) -H. Haber 29-167