Abstract:stereochemistry stereochemistry (general, optical resolution) O 0030
-022New Homochiral Ketoalcohols from Aldol Reactions of (+)-Isomenthone and Reversal of Diastereoselectivity.-Aldol reactions of the enolate derived from isomenthone (I) proceed with complete diastereoselectivity at C-6, but the stereochemical outcome of the attack on the aldehyde carbon is unexpectedly reversed by changing the reaction quenching temperature. -(CHUGHTAI, J. H.; GARDINER, J. M.; HARRIS, S. G.; PARSONS, S.; RANKIN, D. W. H.; SC… Show more
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