ChemInform Abstract: N,N‐Bis(trimethylsilyl)‐S‐methyldithiocarbazate. Preparation, Molecular Structure, and Reactions with Titanium, Niobium, Tantalum, and Molybdenum Halides.

Abstract

The title compound (III) crystallizes in Pn21a with Z = 8. It does not react with Cp2TiCl2, CpTiCl3, CpMCl4 (Cp: π‐cyclopentadienyl) and MCl5 (M: Nb, Ta), probably due to a steric shielding of the reactive nitrogen in (III).