ChemInform Abstract: Mixed Pentasupertetrahedral P1 and Supertetrahedral T2 Clusters as Building Units to Create Two‐Dimentional Indium Chalcogenides Open Framework.

Abstract

Reddish crystals of the new open framework clusters [In12S21(Se3)H2]10‐ are hydrothermally prepared from an aqueous mixture of In, S, Se, NaOH, 4,4′‐trimethylene dipiperidine (TMDP), and histidine (autoclave, 150 °C, 3 d, <55% yield).