1975
DOI: 10.1002/chin.197523418
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ChemInform Abstract: METALLTHIOCYANAT‐KOMPLEXE MIT O‐, M‐ UND P‐METHOXYBENZOYLHYDRAZIN

Abstract: Durch Reaktionen entsprechender Metall(ll)‐isothiocyanate mit stöchiometrischen Mengen von 0‐, m‐ oder p‐Methoxybenzoylhydrazin in wäßrigen Lösungen, ggf. unter Erwärmung, werden die Komplexe (I) dargestellt.

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“…This lack of understanding can be ascribed to the complexity of the chemistry taking place during crystallization, where DMF can also play a major role in the process of SBU formation, as already demonstrated for other MOFs [147,171,172], by virtue of its coordinative character. As a matter of fact, several zirconium complexes featuring DMF as a ligand are known to exist [173][174][175][176]. A contribution might come from the mechanistic studies previously carried out on molecular clusters [141,177,178], although these are usually synthesized in rather different conditions and are soluble in many solvents, which makes them much easier to be characterized insitu.…”
Section: Unravelling the Crystallization Mechanismmentioning
confidence: 99%
“…This lack of understanding can be ascribed to the complexity of the chemistry taking place during crystallization, where DMF can also play a major role in the process of SBU formation, as already demonstrated for other MOFs [147,171,172], by virtue of its coordinative character. As a matter of fact, several zirconium complexes featuring DMF as a ligand are known to exist [173][174][175][176]. A contribution might come from the mechanistic studies previously carried out on molecular clusters [141,177,178], although these are usually synthesized in rather different conditions and are soluble in many solvents, which makes them much easier to be characterized insitu.…”
Section: Unravelling the Crystallization Mechanismmentioning
confidence: 99%