ChemInform Abstract: METALLTHIOCYANAT‐KOMPLEXE MIT O‐, M‐ UND P‐METHOXYBENZOYLHYDRAZIN

Abstract

Durch Reaktionen entsprechender Metall(ll)‐isothiocyanate mit stöchiometrischen Mengen von 0‐, m‐ oder p‐Methoxybenzoylhydrazin in wäßrigen Lösungen, ggf. unter Erwärmung, werden die Komplexe (I) dargestellt.

When defects turn into virtues: The curious case of zirconium-based metal-organic frameworks

“…This lack of understanding can be ascribed to the complexity of the chemistry taking place during crystallization, where DMF can also play a major role in the process of SBU formation, as already demonstrated for other MOFs [147,171,172], by virtue of its coordinative character. As a matter of fact, several zirconium complexes featuring DMF as a ligand are known to exist [173][174][175][176]. A contribution might come from the mechanistic studies previously carried out on molecular clusters [141,177,178], although these are usually synthesized in rather different conditions and are soluble in many solvents, which makes them much easier to be characterized insitu.…”