ChemInform Abstract: Mechanism of Oxidations in Partially Aqueous Media: Kinetics of Oxidation of Thiosemicarbazide and Thiosemicarbazone by Chloramine‐T and Dichloramine‐T in Aqueous Methanol.

Abstract

ChemInform Abstract The oxidation of (I) is of second (zero) order with respect to (IIa) (substrate) and of inverse first order with respect to H+. On using the oxidant (IIb) a change to first order dependence in (IIb) is observed. The kinetics of the oxidation of thiosemicarbazide by (II) show first (fractional) dependence in the concentration of the oxidant (substrate).