ChemInform Abstract: Kinetics and Mechanism of Oxygen Transfer in the Reaction of p‐Cyano‐N,N‐dimethylaniline N‐Oxide with Metalloporphyrin Salts. Part 5. The Influence of Imidazole Ligation of (meso‐Tetrakis(2,6‐dimethylphenyl)porphinato)manganese(III) Chloride on the Rates of Oxygen Transfer from N‐Oxide to Metalloporphyrin Salt and the Efficiency of Oxidations by the Intermediate Higher Valent Manganese‐Oxo Species.

Abstract

The equilibrium constants for mono‐ and bis‐ligation of imidazole with the title porphyrin complex are determined.