ChemInform Abstract: Hypophosphorous Acid as a Hydride Ion Donor.

Karpeiskaya, O. A.; Белый, А. С.; Parnes, Elad; Vol'pin, M. E.

doi:10.1002/chin.198832091

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Deoxygenation Of Carbon Compounds1

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2015

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“…170 Different functions have been tested. However, only triphenylcarbinol was reduced in triphenylmethane 171 with a good yield of 93% and recently exemplified. 172 Currently, sodium hypophosphite has been used for the reduction of graphene oxide containing oxygenated functions, such as carboxylic acids, epoxides, alcohols and ethers, to graphene.…”

Section: Deoxygenation Of Carbon Compoundsmentioning

confidence: 99%

Synthetic applications of hypophosphite derivatives in reduction

et al. 2015

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The development of new tools for the reduction of organic functions to reach high chemo- and stereo-selectivity is an important research domain. Although, aluminum and boron hydrides are commonly used, they suffer from environmentally and safety issues. In particular, at industrial scale, the search for more specific and efficient reagents with a lower ecological impact remains one of the main objectives of organic chemists. This review captures highlights from literature concerning phosphonic and phosphinic acid derivatives as reducing agents and evaluates their potential as alternatives, in particular to boron and aluminum hydrides.

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Section: Deoxygenation Of Carbon Compoundsmentioning

confidence: 99%