ChemInform Abstract: Hydroalumination of Thioacetylenes: A Versatile Generation and Reactions of α‐Aluminate Sulfides Intermediates.

Abstract

Thioethers Q 0580 Hydroalumination of Thioacetylenes: A Versatile Generation and Reactions of α-Aluminate Sulfides Intermediates. -A method is developed for the synthesis of (Z)-and (E)-vinyl sulfides (II) and (III) and the corresponding iodinated compounds (IV) and (V). Starting from (Va), phenylthioallylic alcohol (VII) is obtained with total retention of stereochemistry. -(GUERRERO*, P. G. J.; DABDOUB, M. J.; MARQUES, F. A.; WOSCH, C. L.; BARONI, A. C. M.; FERREIRA, A. G.; Synth.